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Since additive response is mostly considered in risk assessment for mixtures, precautions should be implemented for assessment of toxicity for As-Zn mixture in acidic soil due to their synergistic response in some soils.
Competitive and multispecies models for development of terrestrial biotic ligand models. Toxicity of cationic toxicants to terrestrial receptors is known to be dependent on several soil solution properties.
The importance of accounting for solution pH is heightened in terrestrial systems, since the variation in pH between soils is more marked than that observed between aquatic systems.
Toxicity incurred by trivalent cations e. Al III , Cr III have been related to hydrolysis products in addition to the free metal species, since hydrolysis products are prominent at environmental pH values.
The pKa values for trivalent cations are typically low, resulting in a high proportion of hydrolysis products at low pH.
It is proposed that the appropriate model depends on the physical properties of the element, specifically the acidity of the cation as indicated by pKa values.
Phytocapping of mine waste at Derelict mine sites in New South Wales. Jun Spoil to soil: Historically, mining of metalliferous ore bodies was a relatively dispersed activity, with numerous small mines occurring throughout many western countries including the United States, the United Kingdom, and Australia Soucek et al.
Many metalliferous mine sites began operation in the late eighteenth and early nineteenth centuries and were abandoned in most instances before the environmental movement in Western countries.
As such, there was very little recognition of the potential impacts caused by the dispersal of metal toxicants such as arsenic As , cadmium Cd , copper Cu , lead Pb , and zinc Zn into the surrounding environments from these sites.
Many of these contaminants are cariogenic in humans e. As a result of the lack of regard for potential impacts, much of the mining waste was discarded carelessly throughout mining sites, and in some cases, directly into nearby watercourses.
In this study, three native Australian grasses namely Iseilema membranaceum Barcoo , Dichanthium sericeum Queensland Blue and Sporobolus africanus Tussock were grown in three different soils spiked with different concentrations of inorganic mercury and the root elongation was monitored up to 28 days following the germination.
Results showed that mercury at certain concentrations significantly inhibited the root growth of all three tested native grasses grown in three soils, however, the toxicity was less in the soil with high organic carbon content and acidic pH.
However, the EC10 values indicated that existing guideline values for mercury may be of protective to the native Australian vegetation.
Considering their tolerance to soil mercury, these grass species have the potential for their use in rehabilitation of mercury contaminated sites.
Phytotoxicity of inorganic contaminants is influenced by the presence of competing ions at the site of uptake.
In this study, interaction of soil pore-water constituents with arsenate toxicity was investigated in cucumber Cucumis sativa L using 10 contrasting soils.
Arsenate phytotoxicity was shown to be related to soluble carbonate and phosphate. The data indicated that dissolved phosphate and carbonate had an antagonistic impact on arsenate toxicity to cucumber.
To predict arsenate phytotoxicity in soils with a diverse range of soil solution properties, both carbonate and phosphate were required. The relationship between arsenic and pore-water toxicity parameters was established initially using multiple regression.
In addition, based on the relationship with carbonate and phosphate we successively applied a terrestrial biotic ligand-like model BLM including carbonate and phosphate.
The data indicates that an ion interaction model similar to the BLM for arsenate is possible, potentially improving current risk assessments at arsenic and co-contaminated soils.
Predicting plant uptake of cadmium: Cadmium accumulates in plant tissues at low soil loadings and is a concern for human health. Yet at higher levels it is also of concern for ecological receptors.
We determined Cd partitioning constants for 41 soils to examine the role of soil properties controlling Cd partitioning and plant uptake.
From a series of sorption and dose response studies, transfer functions were developed for predicting Cd uptake in Cucumis sativa L. The dataset was validated with 13 long-term contaminated soils plus 2 control soils ranging in Cd concentration from 0.
The approach may be adapted to a range of plant species. Metal interaction on arsenic toxicity in both in vivo and in vitro biological systems including human cells.
Jun Arsenic Research and Global Sustainability. Predicting plant uptake and toxicity of lead Pb in long-term contaminated soils from derived transfer functions.
Regulatory assessment of lead Pb in contaminated soils is still expressed primarily as total Pb concentrations in soil. From a series of dose-response studies, we developed transfer functions predicting Pb uptake in C.
Further validation is needed in soils with higher pore-water Pb solubility. Sorption parameters as a predictor of arsenic phytotoxicity in Australian soils.
Bioaccessibility of barium from barite contaminated soils based on gastric phase in vitro data and plant uptake. Barite contamination of soil commonly occurs from either barite mining or explorative drilling operations.
This work reported in vitro data for barite contaminated soils using the physiologically based extraction test PBET methodology. The existence of barite in plant tissue and the possibility of 'biomineralised' zones was also investigated using Scanning Electron Microscopy.
Soils with low barium Ba concentrations showed a higher proportion of Ba extractability than barite rich samples. Barium uptake to spinach from soil was different between short term spiking studies and field weathered soils.
Furthermore, Ba crystals were not evident in spinach tissue or acid digest solutions grown in barium nitrate spiked soils despite high accumulation.
Barite was found in the plant digest solutions from barite contaminated soils only. Although behind Steven Taylor and Fabricio Coloccini in the pecking order, he has turned in some strong performances whenever new manager Chris Hughton played him, especially when Taylor and Coloccini were out injured during various times of the season.
He was released by Newcastle United on 1 June The final result was to Hungary. From Wikipedia, the free encyclopedia. This article uses Western name order when mentioning individuals.
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